catena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ2 O 3:O 1] sesquihydrate]
نویسندگان
چکیده
The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hy-droxy-3-sulfonato-benzoate dianion and to the carboxyl-ate O atom of another dianion. It is also coordinated by two water mol-ecules in an overall octa-hedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O-H⋯O hydrogen bonds into a three-dimensional network.
منابع مشابه
catena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2 O 3:O 1] sesquihydrate]
The 1,10-phenanthroline-chelated Co(II) atom in the polymeric title compound, {[Co(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hy-droxy-3-sulfonato-benzoate dianion and to the carboxyl-ate O atom of another dianion. It is also coordinated by two water mol-ecules in a trans-CoN(2)O(4) octa-hedral environment. The dianion links adjacent met...
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In the title compound, {[Co(C9H4N2O4)(C12H8N2)(H2O)2]·1.5H2O} n , the Co(II) atom is hexa-coordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxyl-ate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water mol-ecules. The dihedral angle between the 1H-benzimidazole-5,6-dicarboxyl-ate and 1,10-phenanthroline ligands is 74.41 (4)°. ...
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In the title complex, [Ni(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is hexa-coordinated by one N and one O atom from two different 1H-benzimidazole-5,6-dicarboxyl-ate ligands, two N atoms from one 1,10-phenanthroline ligand and two water mol-ecules. The flexible 1H-benzimidazole-5,6-dicarboxyl-ate ligands link the Ni(II) centres, forming an infinite zigzag chain parallel t...
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ3 N 3,O:N 1]
In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonato-benzotriazolide dianions, two N atoms from a 1,10-phenanthroline mol-ecule and a sulfonate O atom from a 4-sulfonato-benzotriazolide anion, displaying a distorted ZnN(4)O trigonal-bipyramidal geometry. Each 1,10-phenanthroline ligand displays a bidentate chelatin...
متن کاملcatena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)zinc]-μ-4,4′-bipyridine-κ2 N:N′] dinitrate 4,4′-bipyridine hemisolvate monohydrate]
In the title compound, [Zn(C(10)H(8)N(2))(C(12)H(8)N(2))(H(2)O)(2)](NO(3))(2)·0.5C(10)H(8)N(2)·H(2)O, the Zn(II) atom is coordinated in a distorted octa-hedral geometry by two N atoms from two 4,4'-bipyridine (4,4'-bipy) ligands, two N atoms from a chelating 1,10-phenanthroline ligand and two O atoms from two mutually cis water mol-ecules. The 4,4'-bipy ligands bridge the Zn(II) atoms into a ch...
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